function user_role_update( $user_id, $new_role ) {
$site_url = get_bloginfo('wpurl');
$user_info = get_userdata( $user_id );
$to = $user_info->user_email;
$subject = "Role changed: ".$site_url."";
$message = "Hello " .$user_info->display_name . " 亲,您在".$site_url.", 角色已经变为 " . $new_role;
wp_mail($to, $subject, $message);
}
add_action( 'set_user_role', 'user_role_update', 10, 2);